The Food City 500 at Bristol Motor Speedway will have the brothers of Kyle and Kurt Busch on the front row.
It is the third time the two have started a Cup race on the front row together.
Completing the top five are Brad Keselowski, Ricky Stenhouse Jr. and Ryan Blaney.
Kevin Harvick, who has three wins through the first seven races of this year, will start last after going to a backup car following an incident in practice.
Jimmie Johnson also will start at the rear because his team made a tire change after qualifying.